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Oct 9, 2010 · The use of cross-coupling reactions for the preparation of new alkylated or arylated heteroaromatic compounds has increased tremendously over the past two decades. Among all …

The use of N -oxides in butanol as solvent enables a site-selective oxidation of vicinal bis (boronates) with good efficiency and selectivity across a range of substrates to provide 2-hydro …

Apr 1, 2017 · In the field of boronic derivatives, the Suzuki cross-coupling reaction allows the synthesis of non-symmetrical biaryl compounds from the reaction of an aryl halide with an aryl …

Christopher Sandford and Varinder K. Aggarwal * The formation of highly enantioenriched boronic esters through both stoichiometric and catalytic methods has received much attention over the …

The invention provides a novel synthesis process for 4-phenyl-1-butanol. According to the process, tetrahydrofuran is used as a raw material and rapidly and moderately reacts with acyl …

The Grignard reagents may be preformed or generated from an alkyl, alkenyl, aryl, arylalkyl, heteroaryl, vinyl, or allyl halide compound and Mg°. When the boron-containing substrate is a …

Introduction: Boronic acids and their derivatives are powerful chemical building blocks in organic synthesis.[1] This is due to the combination of their stability under ambient conditions, broad …

The resulting radical anions undergo a radical-polar crossover reaction and a 1,2-alkyl/aryl shift from boron to the α-carbon sp 2 center eventually provides valuable secondary and tertiary …

and tertiary alkyl boronic esters have spanned over five decades and are underpinned by a wealth of reactivity platforms, drawing on the unique and varied reactivity of boron. This review …

alkylated boronic esters 3.5a-i as colorless oil in 26-62% yield (Table 3.1). In comparison to alkylation procedures of substrates that do not contain boron, the yields of these reactions are

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